Morpholinium 2,4,6-trinitrophenolate
نویسندگان
چکیده
There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (-). The morpholinium cations in both mol-ecules are puckered and adopt a chair conformation. Intermolecular N-H⋯O and C-H⋯O inter-actions generate rings of motifs R(2) (1)(5) and R(1) (2)(6). The supra-molecular aggregation is completed by the presence of two co-operative hydrogen-bonded networks of further N-H⋯O inter-actions, which generate an infinite one-dimensional chain along the base vector [100]. Two C-H⋯π interactions are also seen.
منابع مشابه
Morpholinium styphnate
In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra-molecular O-H⋯O hydrogen bond occurs in the anion. ...
متن کاملPoly[[tetra-μ2-aqua-diaqua-μ6-oxalato-barium(II)] 2,4,6-trinitrophenolate monohydrate]. Corrigendum
In the paper by Hong, Song & Wu [Acta Cryst. (2007), E63, o2296], the scheme shows the wrong structure. The correct scheme is shown below and the compound name is corrected to "poly[[di-μ(2)-aqua-diaqua-hemi-μ(6)-oxalato-barium(II)] 2,4,6-trinitro-phenolate monohydrate", {[Ba(C(2)O(4))(0.5)(H(2)O)(4)]C(6)H(2)N(3)O(7)·H(2)O}(n).[This corrects the article DOI: 10.1107/S1600536807038159.].
متن کامل1,4-Diazoniabicyclo[2.2.2]octane bis(2,4,6-trinitrophenolate)
In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (-), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter-molecular N-H⋯O hydrogen bonds. The trimeric units are further connected by π-π inter-actions [centroid-centroid distances = 3.507 (2)-3.660 (3) Å], forming laye...
متن کاملN,N-Dimethylanilinium 2,4,6-trinitrophenolate
In the title compound, C(8)H(12)N(+)·C(6)H(2)N(3)O(7) (-), there are N-H⋯O and C-H⋯O inter-actions which generate R(2) (1)(5), R(2) (1)(6) and R(1) (2)(6) ring motifs. The supra-molecular aggregation is completed by the presence of edge-to-face and offset face-to-face π-π inter-actions with centroid-centroid distances of 3.673 and 3.697 Å, respectively.
متن کامل2-Methoxyanilinium 3-hydroxy-2,4,6-trinitrophenolate
The cation and anion of the title mol-ecular salt, C(7)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), are linked via an N-H⋯O hydrogen bond. An intra-molecular O-H⋯O hydrogen bond is also found in the anion. In the crystal, the anions self-assemble via O-H⋯O hydrogen bonds, forming a C(9) supra-molecular chain the b axis. Further inter-molecular N-H⋯O inter-actions also occur.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2008